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Hydrophobic Hydration Processes: Intensity Entropy and Null Thermal Free Energy and Density Entropy and Motive Free Energy.


ABSTRACT:

SUBMITTER: Fisicaro E 

PROVIDER: S-EPMC6881836 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Hydrophobic Hydration Processes: Intensity Entropy and Null Thermal Free Energy and Density Entropy and Motive Free Energy.

Fisicaro Emilia E   Compari Carlotta C   Braibanti Antonio A  

ACS omega 20191111 22


The processes at the molecule level, which are the source of the ergodic properties of thermodynamic systems, are analyzed with special reference to entropy. The entropy change produced by increasing the temperature <i>T</i> depends on the increase of velocity of the particles with a decrease of the squared mean sojourn time (τ<sub>m</sub> <sup>2</sup>) and gradual loss of instant energy intensity. The diminution, which is due to dilution, of the number of terms in the summation of cumulative so  ...[more]

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