A New Cr³⁺ Electrochemical Sensor Based on ATNA/Nafion/Glassy Carbon Electrode.

ABSTRACT: A new electrochemical sensor of metal cation in an aqueous solution based on homobifunctional tridentate disulfide Schiff base and named 1,1'-(-((disulfanediylbis(2,1-phenylene))bis(azaneylylidene))bis(methaneylylidene))bis(naphthalene-2-ol) (ATNA) was easily obtained quantitatively from the condensation reaction of 2-hydroxy-1-naphthaldehyde and2-aminothiophenol, and then fully characterized by spectroscopic techniques for structure elucidation. The molecular structure of ATNA was also confirmed by a single-crystal X-ray diffraction study to reveal a new conformation in which the molecule was stabilized by the O-H…N type intramolecular hydrogen bonding interactions in both moieties. The ATNA was used as a selective electrochemical sensor for the detection of chromium ion (Cr³⁺

SUBMITTER: El-Shishtawy RM 

PROVIDER: S-EPMC7345133 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature