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Heterobimetallic complexes of IrM (M = Fe^II, Co^II, and Ni^II) core and bridging 2-(diphenylphosphino)pyridine: electronic structure and electrochemical behavior.

ABSTRACT: Three complexes based on an Ir-M (M = Fe^II, Co^II, and Ni^II) heterobimetallic core and 2-(diphenylphosphino)pyridine (Ph₂PPy) ligand were synthesized via the reaction of trans-[IrCl(CO)(Ph₂PPy)₂] and the corresponding metal chloride. Their structures were established by single-crystal X-ray diffraction as [Ir(CO)(μ-Cl)(μ-Ph₂PPy)₂FeCl₂]·2CH₂Cl₂ (2), [IrCl(CO)(μ-Ph₂PPy)₂CoCl₂]·2CH₂Cl₂ (3), and [Ir(CO)(μ-Cl)(μ-Ph₂PPy)₂NiCl₂]·2CH₂Cl₂ (4). Time-dependent DFT computations suggest a donor-acceptor interaction between a filled 5d_z² orbital on iridium

SUBMITTER: Cherepakhin V

PROVIDER: S-EPMC7418070 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

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Heterobimetallic complexes of IrM (M = Fe^II, Co^II, and Ni^II) core and bridging 2-(diphenylphosphino)pyridine: electronic structure and electrochemical behavior.

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Dataset Information

Heterobimetallic complexes of IrM (M = FeII, CoII, and NiII) core and bridging 2-(diphenylphosphino)pyridine: electronic structure and electrochemical behavior.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Heterobimetallic complexes of IrM (M = Fe^II, Co^II, and Ni^II) core and bridging 2-(diphenylphosphino)pyridine: electronic structure and electrochemical behavior.