Ontology highlight
ABSTRACT:
SUBMITTER: Holtkamp P
PROVIDER: S-EPMC7986075 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20210128 11
The reactivity of the geminal frustrated Lewis pair (FLP) (F<sub>5</sub> C<sub>2</sub> )<sub>3</sub> SnCH<sub>2</sub> P(tBu)<sub>2</sub> (1) was explored by reacting it with a variety of small molecules (PhOCN, PhNCS, PhCCH, tBuCCH, H<sub>3</sub> CC(O)CH=CH<sub>2</sub> , Ph[C(O)]<sub>2</sub> Ph, PhN=NPh and Me<sub>3</sub> SiCHN<sub>2</sub> ), featuring polar or non-polar multiple bonds and/or represent α,β-unsaturated systems. While most adducts are formed readily, the binding of azobenzene requ ...[more]