Three-dimensional atomic mapping of ligands on palladium nanoparticles by atom probe tomography.

ABSTRACT: Capping ligands are crucial to synthesizing colloidal nanoparticles with functional properties. However, the synergistic effect between different ligands and their distribution on crystallographic surfaces of nanoparticles during colloidal synthesis is still unclear despite powerful spectroscopic techniques, due to a lack of direct imaging techniques. In this study, atom probe tomography is adopted to investigate the three-dimensional atomic-scale distribution of two of the most common types of these ligands, cetrimonium (C₁₉H₄₂N) and halide (Br and Cl) ions, on Pd nanoparticles. The results, validated using density functional theory, demonstrate that the Br anions adsorbed on the nanoparticle surfaces promote the adsorption of the cetrimonium cations through electros

SUBMITTER: Jang K 

PROVIDER: S-EPMC8280228 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature