Trojan Horse Thiocyanate: Induction and Control of High Proton Conductivity in CPO-27/MOF-74 Metal-Organic Frameworks by Metal Selection and Solvent-Free Mechanochemical Dosing.

ABSTRACT: Proton-conducting metal-organic frameworks (MOFs) have been gaining attention for their role as solid-state electrolytes in various devices for energy conversion and storage. Here, we present a convenient strategy for inducing and tuning of superprotonic conductivity in MOFs with open metal sites via postsynthetic incorporation of charge carriers enabled by solvent-free mechanochemistry and anion coordination. This scalable approach is demonstrated using a series of CPO-27/MOF-74 [M₂(dobdc); M = Mg²⁺, Zn²⁺, Ni²⁺; dobdc = 2,5-dioxido-1,4-benzenedicarboxylate] materials loaded with various stoichiometric amounts of NH₄SCN. The modified materials are not achievable by conventional immersion in solutions. Periodic density functional

SUBMITTER: Lupa M 

PROVIDER: S-EPMC8289229 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature