Ontology highlight
ABSTRACT:
SUBMITTER: Corra S
PROVIDER: S-EPMC8367298 | biostudies-literature | 2021 Aug
REPOSITORIES: biostudies-literature
Corra Stefano S de Vet Christiaan C Baroncini Massimo M Credi Alberto A Silvi Serena S
Chem 20210812 8
The mechanical bond has opened a new world for structural and dynamic stereochemistry, which is still largely underexplored and whose significance for various applications is becoming increasingly evident. We demonstrate that designed rearrangements involving both covalent and mechanical bonds can be integrated in [2]rotaxanes, leading to interesting consequences in terms of <i>E/Z</i> isomerization mechanisms. Two entirely distinct and concomitant stereomutations, pertaining to the same stereog ...[more]