Activity of Cu-Al-Oxo Extra-Framework Clusters for Selective Methane Oxidation on Cu-Exchanged Zeolites.

ABSTRACT: Cu-zeolites are able to directly convert methane to methanol via a three-step process using O₂ as oxidant. Among the different zeolite topologies, Cu-exchanged mordenite (MOR) shows the highest methanol yields, attributed to a preferential formation of active Cu-oxo species in its 8-MR pores. The presence of extra-framework or partially detached Al species entrained in the micropores of MOR leads to the formation of nearly homotopic redox active Cu-Al-oxo nanoclusters with the ability to activate CH₄. Studies of the activity of these sites together with characterization by ²⁷Al NMR and IR spectroscopy leads to the conclusion that the active species are located in the 8-MR side pockets of MOR, and it consists of two Cu ions and one Al linked by O. This Cu-Al

SUBMITTER: Lee I 

PROVIDER: S-EPMC8479761 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature