Oxo dicopper anchored on carbon nitride for selective oxidation of methane.

ABSTRACT: Selective conversion of methane (CH₄) into value-added chemicals represents a grand challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric copper centers supported on graphitic carbon nitride (denoted as Cu₂@C₃N₄) as advanced catalysts for CH₄ partial oxidation. The copper-dimer catalysts demonstrate high selectivity for partial oxidation of methane under both thermo- and photocatalytic reaction conditions, with hydrogen peroxide (H₂O₂) and oxygen (O₂) being used as the oxidizer, respectively. In particular, the photocatalytic oxidation of CH₄ with O₂ achieves >10% conversion, and >98% selectivity toward methyl oxygenates and a mass-specific a

SUBMITTER: Xie P 

PROVIDER: S-EPMC8927601 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature