Synergistic regulation of nonbinary molecular switches by protonation and light.

ABSTRACT: We report a molecular switching ensemble whose states may be regulated in synergistic fashion by both protonation and photoirradiation. This allows hierarchical control in both a kinetic and thermodynamic sense. These pseudorotaxane-based molecular devices exploit the so-called Texas-sized molecular box (cyclo[2]-(2,6-di(1H-imidazol-1-yl)pyridine)[2](1,4-dimethylenebenzene); 1⁴⁺, studied as its tetrakis-PF₆ ^- salt) as the wheel component. Anions of azobenzene-4,4'-dicarboxylic acid (2H⁺•2) or 4,4'-stilbenedicarboxylic acid (2H⁺•3) serve as the threading rod elements. The various forms of 2 and 3 (neutral, monoprotonated, and diprotonated) interact differently with 1⁴⁺, as do the photoinduced cis or trans forms

SUBMITTER: Zhang X 

PROVIDER: S-EPMC8617463 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature