Fabricating Na/In/C Composite Anode with Natrophilic Na-In Alloy Enables Superior Na Ion Deposition in the EC/PC Electrolyte.

ABSTRACT: In conventional ethylene carbonate (EC)/propylene carbonate (PC) electrolyte, sodium metal reacts spontaneously and deleteriously with solvent molecules. This significantly limits the practical feasibility of high-voltage sodium metal batteries based on Na metal chemistry. Herein, we present a sodium metal alloy strategy via introducing NaIn and Na₂In phases in a Na/In/C composite, aiming at boosting Na ion deposition stability in the common EC/PC electrolyte. Symmetric cells with Na/In/C electrodes achieve an impressive long-term cycling capability at 1 mA cm^-2 (> 870 h) and 5 mA cm^-2 (> 560 h), respectively, with a capacity of 1 mAh cm^-2. In situ optical microscopy clearly unravels a stable Na ion dynamic deposition process on the Na/In/C compo

SUBMITTER: Wang H 

PROVIDER: S-EPMC8660945 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature