Hydrogen Bond Patterns of Dipyridone and Bis(Hydroxypyridinium) Cations.

ABSTRACT: Dipyridonyl-substituted derivatives 2-4 of benzene, pyridine, and pyrazine, respectively, were synthesized to examine the ability of 2-pyridone and its protonated species to direct the self-assembly by hydrogen bonding. Structural analysis by single-crystal X-ray diffraction (SCXRD) of 2 and 4 in trifluoroacetic acid demonstrated that salts are formed as a result of the transfer of protons from the acid to the base (organic species) to generate a bis(hydroxypyridinium) dication. However, if no proton transfer takes place like in the case of crystals of 3 grown from DMSO/H₂O, the self-assembly is mainly directed by the typical R ₂ ²(8) hydrogen bond motif of 2-pyridone. These results indicate that the process of converting

SUBMITTER: Mohan M 

PROVIDER: S-EPMC8717534 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature