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Mass spectrometric data on the cluster ions formed in mixtures of sodium dodecyl sulfate with divalent metal salts.

ABSTRACT: This paper reports the data obtained from electrospray mass spectra of sodium dodecyl sulfate (SDS) recorded at different concentrations of electrolytes in the positive and negative ion mode, for five different times of acquisition. Using the Excel program, we show the changes in intensities of the peak assigned to a given cluster ion with increasing acquisition time and increasing salt concentration. Moreover, for DS monomers and dimers the correlations were found between the relative peak intensities, P _Me/Na, and concentration ratios, [Me]/[DS] ([Me] and [DS] are concentrations of metal and dodecyl sulfate ions, respectively). The P _Me/Na values are numerical measures of the competition between metal, Me, and sodium, Na, cations in their binding with DS monomers and dimers. Generally, the data presented herein may be used to predict the type of cluster ions formed in a given mixture of an anionic surfactant with a divalent metal salt and a possible correlation between the peak height of a given cluster ion and the electrolyte concentration and acquisition time. For a broad discussion of the dataset obtained for [Me]/[DS] = 1, please refer to the research article "Interactions of divalent metal cations with headgroups of monomers, dimers, and trimers of anionic surfactant" (Jakubowska, 2021).

SUBMITTER: Jakubowska A

PROVIDER: S-EPMC8867052 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature

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Mass spectrometric data on the cluster ions formed in mixtures of sodium dodecyl sulfate with divalent metal salts.

Jakubowska Anna A

Data in brief 20220212

This paper reports the data obtained from electrospray mass spectra of sodium dodecyl sulfate (SDS) recorded at different concentrations of electrolytes in the positive and negative ion mode, for five different times of acquisition. Using the Excel program, we show the changes in intensities of the peak assigned to a given cluster ion with increasing acquisition time and increasing salt concentration. Moreover, for DS monomers and dimers the correlations were found between the relative peak inte ...[more]

PMID: 35242925

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Project description:The number and type of synthetic chemicals that are being produced worldwide continues to increase significantly. While these industrial chemicals provide numerous benefits, there is no doubt that some have potential to damage the environment and health. Toxicity must be evaluated and use must be carefully controlled and monitored in order to minimize potential damage. DNA microarray technology has become an important new technique in toxicology. We are using the yeast Saccharomyces cerevisiae as a model organism for toxicological study because it is a simple, fast-growing eukaryote that has been thoroughly characterized. In order to evaluate toxicity by newly synthesized or mixture chemicals, toxicity-induced gene expression alteration profiles by known chemicals should be collected. In our study, cells need to be exposed with same experimental cellular condition, semi lethal (IC50), respectively. In the case of SDS (CAS; 151-21-3), the exposure dose was decided as 0.01% by growth curve with continuously diluted exposure. SDS is an anionic surfactant that is suspected to be gastrointestinal or liver toxicant. // Toxicity of anionic detergents determined by Saccharomyces cerevisiae microarray analysis: Sodium n-dodecyl benzene sulfonate (LAS) and sodium dodecyl sulfate (SDS) are popular anionic detergents (surfactants) that are used worldwide and the toxicities of these chemicals have been characterized. We applied these chemicals in a DNA microarray bioassay and determined that the microarray data reflects previous findings and also provides some new information about anionic detergent toxicity. The mRNA expression profiles suggest that LAS and SDS cause damage to membranes and alterations in carbon metabolism, and induce the oxidative stress response. We also found that LAS and SDS induce the pleiotropic drug-resistance network, and that LAS and SDS may be pumped out of yeast cells by this network. Hierarchical clustering of the expression profiles showed that LAS and SDS cause similar features of toxicity and that the toxicity is similar to that of capsaicin but different from that of cadmium and mercury. Keywords: stress response

Dataset Information

Mass spectrometric data on the cluster ions formed in mixtures of sodium dodecyl sulfate with divalent metal salts.

Publications

Mass spectrometric data on the cluster ions formed in mixtures of sodium dodecyl sulfate with divalent metal salts.

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