Spongy titanosilicate promotes the catalytic performance and reusability of WO₃ in oxidative cleavage of methyl oleate.

ABSTRACT: A tungsten containing catalyst catalyzed oxidative cleavage of methyl oleate (MO) by employing H₂O₂ as an oxidant and is known as an efficient approach for preparing high value-added chemicals, however, the tungsten leaching problem remains unresolved. In this work, a binary catalyst consisting of tungsten oxide (WO₃) and spongy titanosilicate (STS) zeolite is proposed for MO oxidative cleavage. The function of STS in this catalyst is investigated. On the one hand, STS converts MO to 9,10-epoxystearate (MES), which further forms nonyl aldehyde (NA) and methyl azelaaldehydate (MAA) with the catalysis of WO₃. In this way, MO oxidation and hydrolysis that generates unwanted diol product 9,10-dihydroxystearate (MDS) decreases obviously. On the other

SUBMITTER: Xin S 

PROVIDER: S-EPMC8981253 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature