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Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents.

ABSTRACT: Derivatives of main group elements containing element-element bonds are characterized by unique properties due to σ-conjugation, which is an attractive subject for investigation. A novel series of digermanes, Ar3Ge-Ge(SiMe3)3, containing aryl (Ar = p-C6H4Me (1), p-C6H4F (2), C6F5 (3)) and trimethylsilyl substituents, was synthesized by the reaction of germyl potassium salt, [(Me3Si)3GeK*THF], with triarylchlorogermanes, Ar3GeCl. The optical and electronic properties of such substituted oligoorganogermanes were investigated spectroscopically by UV/vis absorption spectroscopy and theoretically by DFT calculations. The molecular structures of compounds 1 and 2 were studied by XRD analysis. Conjugation between all structural fragments (Ge-Ge, Ge-Si, Ge-Ar, where Ar is an electron-donating or withdrawing group) was found to affect the properties.

SUBMITTER: Zaitsev KV

PROVIDER: S-EPMC9000802 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

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Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents.

Zaitsev Kirill V KV Poleshchuk Oleg Kh OK Churakov Andrei V AV

Molecules (Basel, Switzerland) 20220326 7

Derivatives of main group elements containing element-element bonds are characterized by unique properties due to σ-conjugation, which is an attractive subject for investigation. A novel series of digermanes, Ar3Ge-Ge(SiMe3)3, containing aryl (Ar = p-C6H4Me (1), p-C6H4F (2), C6F5 (3)) and trimethylsilyl substituents, was synthesized by the reaction of germyl potas ...[more]

PMID: 35408545

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Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents.

Publications

Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents.

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