One-dimensional lead iodide hybrid stabilized by inorganic hexarhenium cluster cations as a new broad-band emitter.

ABSTRACT: A novel one-dimensional (1D) hybrid {[Re₆S₈(PzH)₆][Pb₃I₈(DMF)₂]}·6(DMF) with hexarhenium cluster cations has been synthesized and characterized by means of single-crystal X-ray diffraction. Two DMF oxygen atoms bridge three lead iodides to form a set of lead iodides, {[PbI_4/2I(O_DMF)_1/2][PbI_4/2(O_DMF)_2/2][PbI_4/2I(O_DMF)_1/2]}^2-, and these sets of lead iodide share edges to form a 1D lead iodide chain, [Pb₃I₈(DMF)₂]^2- which has never been reported before and is different from the typical edge sharing of octahedral PbI₆ units. 1D lead iodide chains are stacked along th

SUBMITTER: Ly GT 

PROVIDER: S-EPMC9036903 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature