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A facile template-assisted electrodeposition approach to porous Cu/Cu2O nanowires.


ABSTRACT: Although nanoporous materials have been fabricated by electrodeposition using micelles of P-123 as structure-directing entities, the possible geometry obtained has been limited to nanoporous films. Herein, a novel dual-template assisted electrodeposition method to fabricate Cu/Cu2O porous nanowires (PNs) using polymeric micelles as a soft template and polycarbonate membranes as a hard template is reported. These nanowires consist of a porous skeleton with nanosized pores of 20 nm on average and crystallized ligaments. Morphology, composition, and crystal structure are systematically investigated and the formation mechanism is discussed. The as-deposited Cu/Cu2O PNs are found to exhibit high electrocatalytic activity toward electroreduction of nitrate. At an applied ca

SUBMITTER: Zhang J 

PROVIDER: S-EPMC9041089 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature