A series of guanidine salts of 3,6-bis-nitroguanyl-1,2,4,5-tetrazine: green nitrogen-rich gas-generating agent.

ABSTRACT: Nitrogen-rich energetic materials (EMs) have been widely studied because of their high thermal stability, insensitivity, excellent detonation performance and non-toxic characteristics. In particular, these compounds are well applied as gas-generating agents (GGAs). As a nitrogen-rich heterocyclic framework, 1,2,4,5-tetrazine derivatives have shown great potential in the design of GGAs. The guanidine salts of 3,6-bis-nitroguanyl-1,2,4,5-tetrazine (DNGTz), guanidine (G₂DNGTz) (1), aminoguanidine (AG₂DNGTz) (2), diaminoguanidine (DAG₂DNGTz) (3), and triaminoguanidine (TAG₂DNGTz) (4) have been synthesized and characterized by elemental analysis and FT-IR. The crystal structures of 1 and 2 were obtained by X-ray single crystal diffraction. Crystal ana

SUBMITTER: Cong Z 

PROVIDER: S-EPMC9056960 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature