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Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes.


ABSTRACT: The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.

SUBMITTER: Matheny JP 

PROVIDER: S-EPMC9058510 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

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Facile assembly of 1,5-diazocan-2-ones <i>via</i> cyclization of tethered sulfonamides to cyclopropenes.

Matheny Jonathon P JP   Yamanushkin Pavel M PM   Petillo Peter A PA   Rubin Michael M  

RSC advances 20201215 72


The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones. ...[more]

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