High proton conductivity behavior in a 2D metal sulfite constructed from a histidine ligand.

ABSTRACT: In the presence of the amino acid histidine, an inorganic-organic hybrid metal sulfite, Zn₂(SO₃)₂(C₆N₃O₂H₉)₂·H₂O (1), has been prepared under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 shows a 2D layer framework built up from a classical second building unit (S4R), and bridged histidine molecule. Notably, it is the first report of a metal sulfite in the presence of an amino acid molecule. A 1D H-bonding array can be constructed by the H-bonding interaction between histidine molecules and sulfite groups. Moreover, a new function of metal sulfite for proton conduction was investigated by alternating-current impedance analysis. The results demonstrate that

SUBMITTER: Ma Y 

PROVIDER: S-EPMC9064370 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature