Unknown

Dataset Information

0

Heterogeneous Suzuki-Miyaura coupling of heteroaryl ester via chemoselective C(acyl)-O bond activation.


ABSTRACT: A site-selective supported palladium nanoparticle catalyzed Suzuki-Miyaura cross-coupling reaction with heteroaryl esters and arylboronic acids as coupling partners was developed. This methodology provides a heterogeneous catalytic route for aryl ketone formation via C(acyl)-O bond activation of esters by successful suppression of the undesired decarbonylation phenomenon. The catalyst can be reused and shows high activity after eight cycles. The XPS analysis of the catalyst before and after the reaction suggested that the reaction might be performed via a Pd0/PdII catalytic cycle that began with Pd0.

SUBMITTER: Ma H 

PROVIDER: S-EPMC9064562 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

altmetric image

Publications

Heterogeneous Suzuki-Miyaura coupling of heteroaryl ester <i>via</i> chemoselective C(acyl)-O bond activation.

Ma Hongpeng H   Bai Chaolumen C   Bao Yong-Sheng YS  

RSC advances 20190501 30


A site-selective supported palladium nanoparticle catalyzed Suzuki-Miyaura cross-coupling reaction with heteroaryl esters and arylboronic acids as coupling partners was developed. This methodology provides a heterogeneous catalytic route for aryl ketone formation <i>via</i> C(acyl)-O bond activation of esters by successful suppression of the undesired decarbonylation phenomenon. The catalyst can be reused and shows high activity after eight cycles. The XPS analysis of the catalyst before and aft  ...[more]

Similar Datasets

| S-EPMC8892994 | biostudies-literature
| S-EPMC3663905 | biostudies-literature
| S-EPMC6977462 | biostudies-literature
| S-EPMC2504465 | biostudies-literature
| S-EPMC5304707 | biostudies-literature
| S-EPMC3752378 | biostudies-literature
| S-EPMC9087645 | biostudies-literature
| S-EPMC9778444 | biostudies-literature
| S-EPMC9026024 | biostudies-literature
| S-EPMC4166947 | biostudies-literature