Ontology highlight
ABSTRACT:
SUBMITTER: Ma H
PROVIDER: S-EPMC9064562 | biostudies-literature | 2019 May
REPOSITORIES: biostudies-literature
Ma Hongpeng H Bai Chaolumen C Bao Yong-Sheng YS
RSC advances 20190501 30
A site-selective supported palladium nanoparticle catalyzed Suzuki-Miyaura cross-coupling reaction with heteroaryl esters and arylboronic acids as coupling partners was developed. This methodology provides a heterogeneous catalytic route for aryl ketone formation <i>via</i> C(acyl)-O bond activation of esters by successful suppression of the undesired decarbonylation phenomenon. The catalyst can be reused and shows high activity after eight cycles. The XPS analysis of the catalyst before and aft ...[more]