Unknown

Dataset Information

0

Self-assembled Co0.85Se/carbon nanowires as a highly effective and stable electrocatalyst for the hydrogen evolution reaction.

ABSTRACT: Self-assembled Co0.85Se/carbon nanowires, constructed by Co0.85Se nanoparticles homogenously embedded into carbon nanowires (Co0.85Se@CNWs), have been synthesized through a facile solvothermal reaction and selenylation process. Compared to the bare Co0.85Se NWs, the Co0.85Se@CNW hybrid demonstrates high efficiency and stability for HER. It has a small Tafel slope of 43.4 mV dec-1, a low onset potential of 138 mV vs. RHE, and a high cycling stability with more than 95% current retention after 1500 voltammetry cycles. The outstanding HER performance of Co0.85Se@CNWs is attributed to its unique particle-in-nanowire architecture, which not only prevents the Co0.85Se nanoparticles from aggregation, but also provides a highly conductive CNW matrix to promote the charge transfer in the electrocatalytic reaction, further enhancing the catalytic activity. This work provides a new strategy to rationally design transition metal-based selenide hybrids as highly effective and stable electrocatalysts for HER.

SUBMITTER: Sun B 

PROVIDER: S-EPMC9064657 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Self-assembled Co<sub>0.85</sub>Se/carbon nanowires as a highly effective and stable electrocatalyst for the hydrogen evolution reaction.

Sun Baochen B   Wang Xinqiang X   Yang Dongxu D   Chen Yuanfu Y  

RSC advances 20190501 30

Self-assembled Co<sub>0.85</sub>Se/carbon nanowires, constructed by Co<sub>0.85</sub>Se nanoparticles homogenously embedded into carbon nanowires (Co<sub>0.85</sub>Se@CNWs), have been synthesized through a facile solvothermal reaction and selenylation process. Compared to the bare Co<sub>0.85</sub>Se NWs, the Co<sub>0.85</sub>Se@CNW hybrid demonstrates high efficiency and stability for HER. It has a small Tafel slope of 43.4 mV dec<sup>-1</sup>, a low onset potential of 138 mV <i>vs.</i> RHE, an  ...[more]

Similar Datasets

Unknown Facile Synthesis of Microsphere-like Co<sub>0.85</sub>Se Structures on Nickel Foam for a Highly Efficient Hydrogen Evolution Reaction.
| S-EPMC10608889 | biostudies-literature
Unknown Ru <sub><i>x</i></sub> Se@MoS<sub>2</sub> hybrid as a highly efficient electrocatalyst toward hydrogen evolution reaction.
| S-EPMC9063915 | biostudies-literature
Unknown Temperature-Induced Structure Transformation from Co<sub>0.85</sub>Se to Orthorhombic Phase CoSe<sub>2</sub> Realizing Enhanced Hydrogen Evolution Catalysis.
| S-EPMC9097193 | biostudies-literature
Unknown Nanocatalysis MoS<sub>2</sub>/rGO: An Efficient Electrocatalyst for the Hydrogen Evolution Reaction.
| S-EPMC10819749 | biostudies-literature
Unknown A flower-like CoS<sub>2</sub>/MoS<sub>2</sub> heteronanosheet array as an active and stable electrocatalyst toward the hydrogen evolution reaction in alkaline media.
| S-EPMC9050031 | biostudies-literature
Unknown WS<sub>(1-<i>x</i>)</sub>Se<i><sub>x</sub></i> Nanoparticles Decorated Three-Dimensional Graphene on Nickel Foam: A Robust and Highly Efficient Electrocatalyst for the Hydrogen Evolution Reaction.
| S-EPMC6266445 | biostudies-literature
Unknown Data on a highly stable electrocatalyst of NiCoPt/Graphene-dot nanosponge for efficient hydrogen evolution reaction.
| S-EPMC7522483 | biostudies-literature
Unknown A platinum nanoparticle doped self-assembled peptide bolaamphiphile hydrogel as an efficient electrocatalyst for the hydrogen evolution reaction.
| S-EPMC9419667 | biostudies-literature
Unknown Nanosheets of NiCo<sub>2</sub>O<sub>4</sub>/NiO as Efficient and Stable Electrocatalyst for Oxygen Evolution Reaction.
| S-EPMC6645138 | biostudies-literature
Unknown A Co-MOF-derived Co<sub>9</sub>S<sub>8</sub>@NS-C electrocatalyst for efficient hydrogen evolution reaction.
| S-EPMC8694845 | biostudies-literature