Self-assembled Co_0.85Se/carbon nanowires as a highly effective and stable electrocatalyst for the hydrogen evolution reaction.

ABSTRACT: Self-assembled Co_0.85Se/carbon nanowires, constructed by Co_0.85Se nanoparticles homogenously embedded into carbon nanowires (Co_0.85Se@CNWs), have been synthesized through a facile solvothermal reaction and selenylation process. Compared to the bare Co_0.85Se NWs, the Co_0.85Se@CNW hybrid demonstrates high efficiency and stability for HER. It has a small Tafel slope of 43.4 mV dec^-1, a low onset potential of 138 mV vs. RHE, and a high cycling stability with more than 95% current retention after 1500 voltammetry cycles. The outstanding HER performance of Co_0.85Se@CNWs is attributed to its unique particle-in-nanowire architecture, which not only prevents the Co_0.85Se nanoparticles from aggregation, bu

SUBMITTER: Sun B 

PROVIDER: S-EPMC9064657 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature