A coumarin-dihydroperimidine dye as a fluorescent chemosensor for hypochlorite in 99% water.

ABSTRACT: The hypochlorite anion (OCl^-), a reactive oxygen species (ROS), is an important microbicidal agent in the immune system. Accurate and selective detection of OCl^- in environmental and biological samples by a fluorescent molecular sensor is an important subject. All previously reported sensors, however, have suffered from tedious multi-step synthesis for the sensors and the use of large amounts of organic solvents for the analysis. Herein, we report that a coumarin-dihydroperimidine dye prepared by facile condensation behaves as a fluorescent sensor for OCl^- in 99% water. The sensor exhibits weak fluorescence, but OCl^--selective dehydrogenation of its dihydroperimidine unit creates a strong blue fluorescence. This turn-on fluorescence response faci

SUBMITTER: Shiraishi Y 

PROVIDER: S-EPMC9071195 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature