Activating molecular oxygen with Au/CeO₂ for the conversion of lignin model compounds and organosolv lignin.

ABSTRACT: Au/CeO₂ was demonstrated to be a high efficiency catalyst for the conversion of 2-phenoxyacetophenol (PP-ol) employing O₂ as an oxidant and methyl alcohol as the solvent without using an erosive strong base or acid. Mechanistic investigations, including emission quenching experiments, electron spin-resonance (ESR) and intermediate verification experiments, were carried out. The results verified that the superoxide anion activated by Au/CeO₂ from molecular oxygen plays a vital role in the oxidation of lignin model compounds, and the cleavage of both the β-O-4 and C_α-C_β linkages was involved. Au/CeO₂ also performed well in the oxidative conversion of organosolv lignin under mild conditions (453 K), producing vanillin (10.5 wt%

SUBMITTER: Song WL 

PROVIDER: S-EPMC9072557 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature