Effects of g-C₃N₄ Heterogenization into Intrinsically Microporous Polymers on the Photocatalytic Generation of Hydrogen Peroxide.

ABSTRACT: Graphitic carbon nitride (g-C₃N₄) is known to photogenerate hydrogen peroxide in the presence of hole quenchers in aqueous environments. Here, the g-C₃N₄ photocatalyst is embedded into a host polymer of intrinsic microporosity (PIM-1) to provide recoverable heterogenized photocatalysts without loss of activity. Different types of g-C₃N₄ (including Pt@g-C₃N₄, Pd@g-C₃N₄, and Au@g-C₃N₄) and different quenchers are investigated. Exploratory experiments yield data that suggest binding of the quencher either (i) directly by adsorption onto the g-C₃N₄ (as shown for α-glucose) or (ii) indirectly by absorption into the microporous polymer host environment (as shown for Triton X-100) enhances the overall photochemical H₂O₂ production process. The amphiphilic molecule Triton X-100 is shown to interact only weakly with g-C₃N₄ but strongly with PIM-1, resulting in accumulation and enhanced H₂O₂ production due to the microporous polymer host.

SUBMITTER: Zhao Y 

PROVIDER: S-EPMC9073839 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature