Influence of solution pH on degradation of atrazine during UV and UV/H₂O₂ oxidation: kinetics, mechanism, and degradation pathways.

ABSTRACT: The kinetics, degradation mechanism and degradation pathways of atrazine (ATZ) during sole-UV and UV/H₂O₂ processes under various pH conditions were investigated; the effects of UV irradiation time and H₂O₂ dose were also evaluated. A higher reaction rate was observed under neutral pH conditions in the UV only process. For the UV/H₂O₂ process, a higher reaction rate was observed in acidic solution and the degradation rate of ATZ firstly increased with the increase of concentration of H₂O₂ and then decreased when H₂O₂ concentration exceeded 5 mg L^-1. In addition, qualitative and quantitative analyses of oxidation intermediates of ATZ in aqueous solution during the sole-UV

SUBMITTER: Liu Y 

PROVIDER: S-EPMC9074411 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature