Nonfullerene acceptors comprising a naphthalene core for high efficiency organic solar cells.

ABSTRACT: A fused-ring electron acceptor (FREA) NDIC is designed and synthesized. Inspired by IDIC, NDIC was constructed by replacing the benzene with a naphthalene ring in its core unit. IDIC exhibits an optical bandgap of 1.60 eV and a lower lowest unoccupied molecular orbital (LUMO) energy level of -3.92 eV. In comparison, NDIC displays an optical band gap of 1.72 eV and a higher lying LUMO energy level of -3.88 eV. Due to the higher energy level, inverted devices based on NDIC exhibit a higher open circuit voltage (V _oc) of 0.90 V, which is much higher than that of IDIC (0.77 V). After a series of optimizations, a power conversion efficiency (PCE) of 9.43% was obtained with a PBDB-T:NDIC blend active layer, in comparison, a PCE of 9.19% was achieved based on IDIC. Our results d

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC9076117 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature