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A novel fluorescence phenomenon caused by amine induced ion-exchange between Cd²⁺ and Fe³⁺ ions.

ABSTRACT: A 3D metal-organic framework {[Cd(5-Brp)(dpa)]·0.5DMF·H₂O} _n (1) was successfully synthesized and characterized, which markedly recognized iron ions under the induction of an amino group. With the concentration of Fe³⁺ increasing, the emission of 1 first declined, then enhanced with a red shift and was finally quenched, which was different from the reference compound [Cd(5-Brp)(bpp)(H₂O)] _n (2). This result drew our attention to amine induced ion-exchange. This peculiar phenomenon inspired us to construct an effective ion detector.

SUBMITTER: Jia L

PROVIDER: S-EPMC9076181 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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A novel fluorescence phenomenon caused by amine induced ion-exchange between Cd2+ and Fe3+ ions.

Jia Lei L Xue Zhe Z Zhu Rong-Rong RR Yan Tong T Wang Yu-Na YN Zhang Suo-Shu SS Geng Xiao X Du Lin L Zhao Qi-Hua QH

RSC advances 20191202 68

A 3D metal-organic framework {[Cd(5-Brp)(dpa)]·0.5DMF·H2O} n (1) was successfully synthesized and characterized, which markedly recognized iron ions under the induction of an amino group. With the concentration of Fe3+ increasing, the emission of 1 first declined, then enhanced with a red shift and was finally quenched, which was different from the reference compound [Cd(5-Brp)(bpp)(H2O)] n (2). This result drew our attention t ...[more]

PMID: 35541376

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