UV-mediated hydrophosphinylation of unactivated alkenes with phosphinates under batch and flow conditions.

ABSTRACT: A UV-mediated hydrophosphinylation of unactivated alkenes with H-phosphinates and hypophosphorous acid under radical free conditions is presented. The reaction affords selectively a large number of structurally diverse organophosphorous compounds in moderate to good yields under mild reaction conditions in the presence of an organic sensitizer as catalyst irradiated by UV-A LEDs. Furthermore, the high yielding hydrophosphinylation in continuous flow is disclosed.

SUBMITTER: Gelat F 

PROVIDER: S-EPMC9078595 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature