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Sword-like CuO/CeO₂ composites derived from a Ce-BTC metal-organic framework with superior CO oxidation performance.

ABSTRACT: Porous shape-controllable metal oxide composites derived from a metal-organic framework have gained more and more attention due to their extensive applications. In this paper, sword-like CuO/CeO₂ composites were successfully synthesized by calcination of a strawsheave-like Ce-based metal-organic framework (Ce-BTC) containing suitable Cu loading as self-sacrificial templates at 500 °C. Moreover, sword-like CuO/CeO₂ composites displayed superior catalytic performance for CO oxidation, which was ascribed to a good interfacial contact, easily reducible surface copper species at low temperature and abundant surface lattice oxygen species, more Cu⁺ and oxygen vacancies.

SUBMITTER: Wang Y

PROVIDER: S-EPMC9086374 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Sword-like CuO/CeO2 composites derived from a Ce-BTC metal-organic framework with superior CO oxidation performance.

Wang Yin Y Yang Yiqiang Y Liu Ning N Wang Yuxin Y Zhang Xiaodong X

RSC advances 20180925 58

Porous shape-controllable metal oxide composites derived from a metal-organic framework have gained more and more attention due to their extensive applications. In this paper, sword-like CuO/CeO2 composites were successfully synthesized by calcination of a strawsheave-like Ce-based metal-organic framework (Ce-BTC) containing suitable Cu loading as self-sacrificial templates at 500 °C. Moreover, sword-like CuO/CeO2 composites displayed superior catalytic performance for CO o ...[more]

PMID: 35548131

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