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Highly efficient conversion of CO₂ to cyclic carbonates with a binary catalyst system in a microreactor: intensification of "electrophile-nucleophile" synergistic effect.

ABSTRACT: An intensification of the "electrophile-nucleophile" synergistic effect was achieved in a microreactor for the coupling reaction of CO₂ and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope.

SUBMITTER: Li MR

PROVIDER: S-EPMC9090913 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature

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Highly efficient conversion of CO2 to cyclic carbonates with a binary catalyst system in a microreactor: intensification of "electrophile-nucleophile" synergistic effect.

Li Ming-Ran MR Zhang Ming-Chao MC Yue Tian-Jun TJ Lu Xiao-Bing XB Ren Wei-Min WM

RSC advances 20181123 68

An intensification of the "electrophile-nucleophile" synergistic effect was achieved in a microreactor for the coupling reaction of CO2 and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope. ...[more]

PMID: 35558338

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