Ontology highlight
ABSTRACT:
SUBMITTER: Sharique M
PROVIDER: S-EPMC9116295 | biostudies-literature | 2022 May
REPOSITORIES: biostudies-literature
Chemical science 20220426 19
An operationally simple, open-air, and efficient light-mediated Minisci C-H alkylation method is described, based on the formation of an electron donor-acceptor (EDA) complex between nitrogen-containing heterocycles and redox-active esters. In contrast to previously reported protocols, this method does not require a photocatalyst, an external single electron transfer agent, or an oxidant additive. Achieved under mildly acidic and open-air conditions, the reaction incorporates primary-, secondary ...[more]