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Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra.

ABSTRACT: Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m²·g^-1.

SUBMITTER: Lerma-Berlanga B

PROVIDER: S-EPMC9157491 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

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Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra.

Lerma-Berlanga Belén B Castells-Gil Javier J Ganivet Carolina R CR Almora-Barrios Neyvis N González-Platas Javier J Fabelo Oscar O Padial Natalia M NM Martí-Gastaldo Carlos C

Journal of the American Chemical Society 20211208 50

Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m2·g-1. ...[more]

PMID: 34877864

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