Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra.

ABSTRACT: Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m²·g^-1.

SUBMITTER: Lerma-Berlanga B 

PROVIDER: S-EPMC9157491 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature