A sustainable approach for the synthesis of recyclable cyclic CO₂-based polycarbonates.

ABSTRACT: It is highly desirable to reduce the environmental pollution related to the disposal of end-of-life plastics. Polycarbonates derived from the copolymerization of CO₂ and epoxides have attracted much attention since they can enable CO₂-fixation and furnish biorenewable and degradable polymeric materials. So far, only linear CO₂-based polycarbonates have been reported and typically degraded to cyclic carbonates. Here we synthesize a homogeneous dinuclear methyl zinc catalyst ((BDI-ZnMe)₂, 1) to rapidly copolymerize meso-CHO and CO₂ into poly(cyclohexene carbonate) (PCHC) with an unprecedentedly cyclic structure. Moreover, in the presence of trace amounts of water, a heterogeneous multi-nuclear zinc catalyst ((BDI-(ZnMe₂

SUBMITTER: Liao X 

PROVIDER: S-EPMC9159078 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature