Engineering the Interfacial Microenvironment via Surface Hydroxylation to Realize the Global Optimization of Electrochemical CO₂ Reduction.

ABSTRACT: The adsorption and activation of CO₂ on the electrode interface is a prerequisite and key step for electrocatalytic CO₂ reduction reaction (eCO₂ RR). Regulating the interfacial microenvironment to promote the adsorption and activation of CO₂ is thus of great significance to optimize overall conversion efficiency. Herein, a CO₂-philic hydroxyl coordinated ZnO (ZnO-OH) catalyst is fabricated, for the first time, via a facile MOF-assisted method. In comparison to the commercial ZnO, the as-prepared ZnO-OH exhibits much higher selectivity toward CO at lower applied potential, reaching a Faradaic efficiency of 85% at -0.95 V versus RHE. To the best of our knowledge, such selectivity is one of the best records in ZnO-based catalysts reported

SUBMITTER: Han X 

PROVIDER: S-EPMC9305709 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature