Dataset Information

Exploring the Cobalt-Histidine Complex for Wide-Ranging Colorimetric O₂ Detection.

ABSTRACT: Developing a robust, cost-effective, and user-friendly sensor for monitoring molecular oxygen (O₂) ranging from a minute to a medically relevant level (85-100%) in a stream of flowing breathable gas is vital in various industrial domains. Here, we report an innovative application of the cobalt(l-histidine)₂ complex, a bioinspired model of O₂-carrying metalloproteins, for rapid and reliable sensing of O₂ from 0 to 100% saturation levels under realistic conditions. We have established two distinct colorimetric O₂ detection techniques, which can be executed with the use of a common smartphone camera and readily available color-detecting software. A series of spectroscopic experiments were performed to demonstrate the molecular-level alteration in cobalt(l-histidine)₂ following its exposure to oxygen, leading to an exclusive pink-to-brown color change. Therefore, this study establishes a template for designing bioinspired molecular complexes for O₂ sensing, leading to practical and straightforward solutions. This metal-amino acid complex's broad-spectrum sensing of O₂ has widened the scope of bioinspired model complexes for divergent applications in industrial sectors.

SUBMITTER: Saini A

PROVIDER: S-EPMC9366964 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Exploring the Cobalt-Histidine Complex for Wide-Ranging Colorimetric O2 Detection.

Saini Abhishek A Rai Surabhi S Maiti Debabrata D Dutta Arnab A

ACS omega 20220729 31

Developing a robust, cost-effective, and user-friendly sensor for monitoring molecular oxygen (O2) ranging from a minute to a medically relevant level (85-100%) in a stream of flowing breathable gas is vital in various industrial domains. Here, we report an innovative application of the cobalt(l-histidine)2 complex, a bioinspired model of O2-carrying metalloproteins, for rapid and reliable sensing of O2 from 0 to 100% saturation levels under realistic ...[more]

PMID: 35967046

Similar Datasets

Project description:Sorption-based atmospheric water harvesting (SBAWH) is a highly promising approach for extracting water from the atmosphere thanks to its sustainability, exceptional energy efficiency, and affordability. In this work, ZnFe2O4 and Zn0.4Co0.6Fe2O4 were evaluated for moisture adsorption. The desired materials were synthesized by a surfactant-assisted sol-gel method. Synthesized samples were characterized using X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, vibrating sample magnetometry (VSM), and point of zero charge (PZC). Crystallinity and phase composition were evaluated by XRD analysis. Several parameters were determined using XRD analysis: lattice parameter, unit cell volume, crystallite size, and bulk density. The morphology of synthesized materials was assessed via SEM, and unveiled the acquisition of consistent, homogeneous, and uniform crystals. Elemental composition was determined through EDX spectroscopy. Water adsorption on the surface was evaluated by FTIR spectroscopy. The magnetic properties of synthesized ZnFe2O4 and cobalt-doped ZnFe2O4 ferrites were investigated using VSM. The negative charge on the Zn0.4Co0.6Fe2O4 surface was explored using PZC. Adsorption studies on synthesized materials were conducted with the help of an atmospheric water harvesting (AWH) plant created by our team. Moisture adsorption isotherms of synthesized materials were determined using a gravimetric method under varying temperature and relative humidity (45-95%) conditions. The moisture content (Mc) of Zn0.4Co0.6Fe2O4 and ZnFe2O4 was 597 mg g-1 and 104 mg g-1, respectively. Key thermodynamic properties, including isosteric heat of adsorption (Qst), change in Gibbs free energy (ΔG), and change in sorption entropy (ΔS), were evaluated. Qst was negative, which confirmed the sorption of water vapors on the material surface. ΔG and ΔS indicated that water-vapor adsorption was spontaneous and exothermic. A second-order kinetics study was carried out on synthesized materials, demonstrating their chemisorption behavior. The latter was due to the oxygen defects created by replacement of Co2+ and Fe3+ at tetrahedral and octahedral sites. Water vapors in the atmosphere became attached to the surface and deprotonation occurred, and the hydroxyl ions were formed. Water vapor attached to these hydroxyl ions. A second-order kinetics study was carried out to confirm the chemisorption behavior of synthesized materials.

Dataset Information

Exploring the Cobalt-Histidine Complex for Wide-Ranging Colorimetric O₂ Detection.

Publications

Exploring the Cobalt-Histidine Complex for Wide-Ranging Colorimetric O<sub>2</sub> Detection.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets