Novel Two-Step Process in Cellulose Depolymerization: Hematite-Mediated Photocatalysis by Lytic Polysaccharide Monooxygenase and Fenton Reaction.

ABSTRACT: To transform cellulose from biomass into fermentable sugars for biofuel production requires efficient enzymatic degradation of cellulosic feedstocks. The recently discovered family of oxidative enzymes, lytic polysaccharide monooxygenase (LPMO), has a high potential for industrial biorefinery, but its energy efficiency and scalability still have room for improvement. Hematite (α-Fe₂O₃) can act as a photocatalyst by providing electrons to LPMO-catalyzed reactions, is low cost, and is found abundantly on the Earth's surface. Here, we designed a composite enzymatic photocatalysis-Fenton reaction system based on nano-α-Fe₂O₃. The feasibility of using α-Fe₂O₃ nanoparticles as a composite catalyst to facilitate LPMO-catalyzed cell

SUBMITTER: Wang D 

PROVIDER: S-EPMC9389612 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature