A carbon-coated shuttle-like Fe2O3/Fe1-x S heterostructure derived from metal-organic frameworks with high pseudocapacitance for ultrafast lithium storage.
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ABSTRACT: Pursuing active, low-cost, and stable electrode materials with superior rate capability and long-life cycling performances for lithium-ion batteries remains a big challenge. In this study, a carbon-coated shuttle-like Fe2O3/Fe1-x S heterostructure is synthesized by simply annealing Fe-based metal-organic frameworks (MIL-88(Fe)) as precursors and sublimed sulfur. Carbon-coated Fe2O3/Fe1-x S displays a unique structure with ultrafine Fe2O3/Fe1-x S nanoparticles distributed in the hollow and porous carbon matrix, which offers a large specific surface area and fast charge transfer ability, and alleviates the volume change upon cycling. When evaluated as an anode material for
SUBMITTER: Zhu G
PROVIDER: S-EPMC9417708 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
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