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Doping-free bandgap tunability in Fe₂O₃ nanostructured films.

ABSTRACT: A tunable bandgap without doping is highly desirable for applications in optoelectronic devices. Herein, we develop a new method which can tune the bandgap without any doping. In the present research, the bandgap of Fe₂O₃ nanostructured films is simply tuned by changing the synthesis temperature. The Fe₂O₃ nanostructured films are synthesized on ITO/glass substrates at temperatures of 1100, 1150, 1200, and 1250 °C using the hot filament metal oxide vapor deposition (HFMOVD) and thermal oxidation techniques. The Fe₂O₃ nanostructured films contain two mixtures of Fe²⁺ and Fe³⁺ cations and two trigonal (α) and cubic (γ) phases. The increase of the Fe²⁺ cations and cubic (γ) phase with the elevated synthesis temperatures lifted the valence band edge, indicating a reduction in the bandgap. The linear bandgap reduction of 0.55 eV without any doping makes the Fe₂O₃ nanostructured films promising materials for applications in bandgap engineering, optoelectronic devices, and energy storage devices.

SUBMITTER: Kadam SA

PROVIDER: S-EPMC9418971 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Doping-free bandgap tunability in Fe2O3 nanostructured films.

Kadam Sujit A SA Phan Giang Thi GT Pham Duy Van DV Patil Ranjit A RA Lai Chien-Chih CC Chen Yan-Ruei YR Liou Yung Y Ma Yuan-Ron YR

Nanoscale advances 20210729 19

A tunable bandgap without doping is highly desirable for applications in optoelectronic devices. Herein, we develop a new method which can tune the bandgap without any doping. In the present research, the bandgap of Fe2O3 nanostructured films is simply tuned by changing the synthesis temperature. The Fe2O3 nanostructured films are synthesized on ITO/glass substrates at temperatures of 1100, 1150, 1200, and 1250 °C using the hot filament metal oxide vap ...[more]

PMID: 36133276

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Project description:Delafossite materials are considered to be a promising range of transparent conductive oxides for optoelectronic applications. The complications that have held back their implementation in practical devices lie in the complex growth methods that are required and in the formation of undesirable secondary phases. Herein, a fast, simple, and low-cost deposition method allowing the deposition of high-quality 2H-CuFeO2 nanostructured thin films is employed. The effect of Sr doping on the properties of spray-coated CuFeO2 thin film annealed at 850 °C is reported. X-ray diffraction (XRD) analysis revealed the delafossite structures of all the samples corresponding to the 2H-CuFeO2 phase. The lattice spacing decreased with increasing substitution of Sr at the Cu site. Raman analysis further authenticated the structural results collected via XRD analysis. Surface scanning using field-emission scanning electron microscopy revealed the formation of nanostructured CuFeO2 thin film possessing high crystalline quality, with the nanocrystal size increasing as the dopant content was increased. Energy-dispersive X-ray analysis allowed the quantification of the elements content via determining the ratios of the main elements as well as the dopant content in each sample. The optical properties of the samples showed strong light absorption in the visible region with a decrease in the band gap values with Sr insertion. First-principles calculations using density functional theory (DFT) were conducted to strengthen the experimental findings regarding the nature of the bonds in the hexagonal lattice of the CuFeO2 compound and the effect of Sr doping on its characteristics. The electrical properties measured at room temperature revealed p-type conductivity with tunable resistivity, while the samples displayed increased electron mobility as a function of the dopant content. Consequently, our work introduced an efficient and cost-effective synthesis route for the preparation of high-quality nanostructured 2H-CuFeO2 thin films, paving the way to facilitate further device applications.

Dataset Information

Doping-free bandgap tunability in Fe₂O₃ nanostructured films.

Publications

Doping-free bandgap tunability in Fe<sub>2</sub>O<sub>3</sub> nanostructured films.

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