A comprehensive understanding of carbon-carbon bond formation by alkyne migratory insertion into manganacycles.

ABSTRACT: Migratory insertion (MI) is one of the most important processes underpinning the transition metal-catalysed formation of C-C and C-X bonds. In this work, a comprehensive model of MI is presented, based on the direct observation of the states involved in the coupling of alkynes with cyclometallated ligands, augmented with insight from computational chemistry. Time-resolved spectroscopy demonstrates that photolysis of complexes [Mn(C^N)(CO)₄] (C^N = cyclometalated ligand) results in ultra-fast dissociation of a CO ligand. Performing the experiment in a toluene solution of an alkyne results in the initial formation of a solvent complex fac-[Mn(C^N)(toluene)(CO)₃]. Solvent substitution gives an η²-alkyne complex fac-[Mn(C^N)(η²-R^1<

SUBMITTER: Hammarback LA 

PROVIDER: S-EPMC9431456 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature