Homoatomic cations: From [P₅]⁺ to [P₉].

ABSTRACT: Recent synthetic approaches to a series of [P₉]X salts (X = [F{Al(OR^F)₃}₂], [Al(OR^F)₄], and (R^F = C(CF₃)₃); Ga₂Cl₇) overcome limitations in classical synthesis methods that proved unsuitable for phosphorus cations. These salts contain the homopolyatomic cation [P₉]⁺ via (I) oxidation of P₄ with NO[F{Al(OR^F)₃}₂], (II) the arene-stabilized Co(I) sandwich complex [Co(arene)₂][Al(OR^F)₄] [arene = ortho-difluorobenzene (o-DFB) and fluorobenzene (FB)], or (III) the reduction of [P₅Cl₂][Ga₂Cl₇] with Ga[Ga₂

SUBMITTER: Frotschel-Rittmeyer J 

PROVIDER: S-EPMC9451154 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature