Dataset Information

Europium (II)-Doped CaF₂ Nanocrystals in Sol-Gel Derived Glass-Ceramic: Luminescence and EPR Spectroscopy Investigations.

ABSTRACT: The remarkable properties of Eu²⁺-activated phosphors, related to the broad and intense luminescence of Eu²⁺ ions, showed a high potential for a wide range of optical-related applications. Oxy-fluoride glass-ceramic containing Europium (II)-doped CaF₂ nanocrystals embedded in silica matrix were produced in two steps: glass-ceramization in air at 800° with Eu³⁺-doped CaF₂ nanocrystals embedded followed by Eu³⁺ to Eu²⁺ reduction during annealing in reducing atmosphere. The broad, blue luminescence band at 425 nm and with the long, weak tail in the visible range is assigned to the d → f type transition of the Eu²⁺ located inside the CaF₂ nanocrystals in substitutional and perturbed sites, respectively; the photoluminescence quantum yield was about 0.76. The X-ray photoelectron spectroscopy and Electron paramagnetic spectroscopy confirmed the presence of Eu²⁺ inside the CaF₂ nanocrystals. Thermoluminescence curves recorded after X-ray irradiation of un-doped and Eu²⁺-doped glass-ceramics showed a single dominant glow peak at 85 °C related to the recombination between F centers and Eu²⁺ related hole within the CaF₂ nanocrystals. The applicability of the procedure can be tested to obtain an oxy-fluoride glass-ceramic doped with other divalent ions such as Sm²⁺, Yb²⁺, as nanophosphors for radiation detector or photonics-related applications.

SUBMITTER: Secu C

PROVIDER: S-EPMC9457762 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Publications

Europium (II)-Doped CaF2 Nanocrystals in Sol-Gel Derived Glass-Ceramic: Luminescence and EPR Spectroscopy Investigations.

Secu Corina C Rostas Arpad-Mihai AM Secu Mihail M

Nanomaterials (Basel, Switzerland) 20220831 17

The remarkable properties of Eu2+-activated phosphors, related to the broad and intense luminescence of Eu2+ ions, showed a high potential for a wide range of optical-related applications. Oxy-fluoride glass-ceramic containing Europium (II)-doped CaF2 nanocrystals embedded in silica matrix were produced in two steps: glass-ceramization in air at 800° with Eu3+-doped CaF2 nanocrystals embedded followed by Eu3+ to Eu2+ re ...[more]

PMID: 36080052

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Project description:During the processes associated with glass corrosion, porous hydrated glass alteration layers typically form upon exposure to aqueous conditions for extended time periods. The impacts of the alteration layer on glass durability have not been agreed upon in the glass science community. In particular, the formation mechanisms of hydrated glass alteration layers are still largely unknown and require further investigation, but these layers often require months to years to develop and are often too thin to adequately characterize. Meanwhile, sol-gel-derived silicate gels are relatively easy to synthesize in bulk with custom compositions relevant to hydrated glass alteration layers. If alteration layers and synthetic silicate gels demonstrate physical and chemical properties that are sufficiently similar, synthetic silicate gels could be used as analogues for hydrated glass alteration layers in future studies. However, synthetic gels must first be prepared and evaluated before comparisons between glass alteration layers and synthetic silicate gels can be made. This work focuses entirely on the synthesis and observed physical properties of synthetic silicate gels. A future work will compare the characteristics of synthetic gels described in this work with altered waste glass formed in similar pH environments. In this study, synthetic gels were made with custom compositions at various pH values to evaluate the effect of pH on gel structure and morphology. Several other variables were examined also, such as composition, drying, and aging. Gels were produced by sequential additions of organometallic precursors in a single container. Gels were analyzed with several techniques including small-angle X-ray scattering, gas adsorption, and He pycnometry to determine the effects of the variables on physical properties. Results show that gels prepared at pH 3 consistently contained fewer primary particles with diameters larger than 7.2 nm and fewer pores with diameters larger than 30 nm compared to gels synthesized at pH 7 and 9. Composition was shown to have no discernable effect on primary particle and pore sizes at any pH.

Dataset Information

Europium (II)-Doped CaF₂ Nanocrystals in Sol-Gel Derived Glass-Ceramic: Luminescence and EPR Spectroscopy Investigations.

Publications

Europium (II)-Doped CaF<sub>2</sub> Nanocrystals in Sol-Gel Derived Glass-Ceramic: Luminescence and EPR Spectroscopy Investigations.

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