Self-repairing interphase reconstructed in each cycle for highly reversible aqueous zinc batteries.

ABSTRACT: Aqueous zinc (Zn) chemistry features intrinsic safety, but suffers from severe irreversibility, as exemplified by low Coulombic efficiency, sustained water consumption and dendrite growth, which hampers practical applications of rechargeable Zn batteries. Herein, we report a highly reversible aqueous Zn battery in which the graphitic carbon nitride quantum dots additive serves as fast colloid ion carriers and assists the construction of a dynamic & self-repairing protective interphase. This real-time assembled interphase enables an ion-sieving effect and is found actively regenerate in each battery cycle, in effect endowing the system with single Zn²⁺ conduction and constant conformal integrality, executing timely adaption of Zn deposition, thus retaining sustainable long-term p

SUBMITTER: Zhang W 

PROVIDER: S-EPMC9468148 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature