Accelerated Degradation of Perfluorosulfonates and Perfluorocarboxylates by UV/Sulfite + Iodide: Reaction Mechanisms and System Efficiencies.

ABSTRACT: The addition of iodide (I^-) in the UV/sulfite system (UV/S) significantly accelerated the reductive degradation of perfluorosulfonates (PFSAs, C_nF_2n+1SO₃^-) and perfluorocarboxylates (PFCAs, C_nF_2n+1COO^-). Using the highly recalcitrant perfluorobutane sulfonate (C₄F₉SO₃^-) as a probe, we optimized the UV/sulfite + iodide system (UV/S + I) to degrade n = 1-7 PFCAs and n = 4, 6, 8 PFSAs. In general, the kinetics of per- and polyfluoroalkyl substance (PFAS) decay, defluorination, and transformation product formations in UV/S + I were up to three times faster than those in UV/S. Both systems achieve a similar maximum defluori

SUBMITTER: Liu Z 

PROVIDER: S-EPMC9481055 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature