Deciphering the selectivity descriptors of heterogeneous metal phthalocyanine electrocatalysts for hydrogen peroxide production† † Electronic supplementary information (ESI) available. See https://doi.org/10.1039/d2sc03714a

ABSTRACT: The electrocatalytic 2e− oxygen reduction reaction (2e− ORR) provides an appealing pathway to produce hydrogen peroxide (H2O2) in a decentralized and clean manner, which drives the demand for developing high selectivity electrocatalysts. However, current understanding on selectivity descriptors of 2e− ORR electrocatalysts is still insufficient, limiting the optimization of catalyst design. Here we study the catalytic performances of a series of metal phthalocyanines (MPcs, M = Co, Ni, Zn, Cu, Mn) for 2e− ORR by combining density functional theory calculations with electrochemical measurements. Two descriptors (ΔG*O − ΔG*OOH and ΔG*H2O2) are uncovered for manipulating the selectivity of H2O2 production. ΔG*O − ΔG*OOH reflects the preference of O–O bond breaking of *OOH, affecting the intrinsic selectivities. Due to the high value of ΔG*O − ΔG*OOH, the molecularly dispersed electrocatalyst (MDE) of ZnPc on carbon nanotubes exhibits high selectivity, even superior to the previously reported NiPc MDE. ΔG*H2O2 determines the possibility of further H2O2 reduction to affect the measured selectivities. Enhancing the hydrophobicity of the catalytic layer can increase ΔG*H2O2, leading to selectivity improvement, especially under high H2O2 production rates. In the gas diffusion electrode measurements, both ZnPc and CoPc MDEs with polytetrafluoroethylene (PTFE) exhibit low overpotentials, high selectivities, and good stability. This study provides guidelines for rational design of 2e− ORR electrocatalysts. Two selectivity descriptors for the 2e− oxygen reduction reaction are found on molecularly dispersed electrocatalysts of metal phthalocyanines anchored on carbon nanotubes. The optimized catalysts can produce H2O2 with high selectivity at high rates.

SUBMITTER: Yuan Y 

PROVIDER: S-EPMC9516951 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature