Insights into memory effect mechanisms of layered double hydroxides with solid-state NMR spectroscopy.
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ABSTRACT:
SUBMITTER: Jin L
PROVIDER: S-EPMC9568524 | biostudies-literature | 2022 Oct
REPOSITORIES: biostudies-literature
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Insights into memory effect mechanisms of layered double hydroxides with solid-state NMR spectroscopy.
Jin Li L Zhou Xiaoyuan X Wang Fang F Ning Xiang X Wen Yujie Y Song Benteng B Yang Changju C Wu Di D Ke Xiaokang X Peng Luming L
Nature communications 20221014 1
Layered double oxides (LDOs) can restore the parent layered double hydroxides (LDHs) structure under hydrous conditions, and this "memory effect" plays a critical role in the applications of LDHs, yet the detailed mechanism is still under debate. Here, we apply a strategy based on ex situ and in situ solid-state NMR spectroscopy to monitor the Mg/Al-LDO structure changes during recovery at the atomic scale. Despite the common belief that aqueous solution is required, we discover that the structu ...[more]
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