Entropy-Driven Thermo-gelling Vitrimer.

ABSTRACT: Thermo-gelling polymers have been envisioned as promising smart biomaterials but limited by their weak mechanical and thermodynamic stabilities. Here, we propose a new thermo-gelling vitrimer, which remains at a liquid state because of the addition of protector molecules preventing the crosslinking, and with increasing temperature, an entropy-driven crosslinking occurs to induce the sol-gel transition. Moreover, we find that the activation barrier in the metathesis reaction of vitrimers plays an important role, and experimentally, one can use catalysts to tune the activation barrier to drive the vitrimer to form an equilibrium gel at high temperature, which is not subject to any thermodynamic instability. We formulate a mean-field theory to describe the entropy-driven crosslinking of the v

SUBMITTER: Xia X 

PROVIDER: S-EPMC9597860 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature