Self-healing mixed matrix membranes containing metal-organic frameworks.

ABSTRACT: Mixed-matrix membranes (MMMs) provide a means to formulate metal-organic frameworks (MOFs) into processable films that can help to advance their use in various applications. Conventional MMMs are inherently susceptible to craze or tear upon exposure to impact, cutting, bending, or stretching, which can limit their intended service life and usage. Herein, a simple, efficient, and scalable in situ fabrication approach was used to prepare self-healing MMMs containing Zr(iv)-based MOFs. The ability of these MMMs to self-heal at room temperature is based on the reversible hydrolysis of boronic-ester conjugates. Thiol-ene 'photo-click' polymerization yielded robust MMMs with ∼30 wt% MOF loading and mechanical strength that varied based on the size of MOF particles. The MMMs could undergo

SUBMITTER: Mondal P 

PROVIDER: S-EPMC9601252 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature