Simultaneously tuning interlayer spacing and termination of MXenes by Lewis-basic halides.

ABSTRACT: The surface and interface chemistry are of significance on controlling the properties of two-dimensional transition metal carbides and nitrides (MXenes). Numerous efforts have been devoted to the regulation of Ti₃C₂T_x MXene, however, tuning interlayer spacing and surface halogen termination of other MXenes (besides Ti₃C₂T_x) is rarely reported while demanded. Here we propose a Lewis-basic halides treatment, which is capable of simultaneously engineering the interlayer spacing and surface termination of various MXenes. Benefited from the abundant desolvated halogen anions and cations in molten state Lewis-basic halides, the -F termination was substituted by nucleophilic reaction and the interlayer spacing was enlarged. Ti

SUBMITTER: Zhang T 

PROVIDER: S-EPMC9643510 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature