P-C, P-N, and M-N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three- to Five-Membered Phosphametallacycles.

ABSTRACT: Reactions of the heterometallic MoRe complex [MoReCp(μ-PR*)(CO)₆] and its MoMn analogue with some small molecules having N-N multiple bonds, such as diazoalkanes and organic azides, were investigated (R* = 2,4,6-C₆H₂^tBu₃). Reactions with excess ethyl diazoacetate proceeded slowly and with concomitant denitrogenation to give complexes [MoMCp(μ-η²_P,C:κ²_P,O-PR*CHCO₂Et)(CO)₅], which display a bridging phosphaalkene ligand in a novel μ-η²:κ² coordination mode, while reactions with other diazoalkanes resulted only in the decomposition of the organic reagent. The MoRe complex reacted with benzyl- or p-tolyl azide at room temperature to give t

SUBMITTER: Alvarez MA 

PROVIDER: S-EPMC9682477 | biostudies-literature | 2022 Nov

REPOSITORIES: biostudies-literature